Two-step magnetic switching in a mononuclear iron(II) complex around room temperature.

نویسندگان

  • Qian Yang
  • Xin Cheng
  • YeXin Wang
  • BingWu Wang
  • ZheMing Wang
  • Song Gao
چکیده

A neutral mononuclear Fe(II) complex with spin crossover (SCO) properties, Fe2(SCN)2 (1) (L = 2-(2-(trifluoromethyl)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), was solvothermally synthesized. It displays a new example of two-step SCO with Tc1↓ = 250 K, Tc1↑ = 260 K and Tc2 = 295 K.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 19  شماره 

صفحات  -

تاریخ انتشار 2015